New paper published in Desalination, led by the Gallei Group, on the capture and release of per- and polyfluoroalkyl substances by use of polyelectrolyte metallopolymers.

New paper published in Separation and Purification Technology on “Optimized electrochemical recovery of lithium-ions from spent battery cells using carbon-coated lithium iron phosphate”. We optimized a system based on carbon-coated lithium iron phosphate electrodes. The electrodes selectively extract lithium ions from complex leaching solutions derived from real LCO (LiCoO₂) cathode materials. Over the course of 300 cycles, we observed an average lithium uptake capacity of about 11 mg of Li-ions per 1 gram of active material per cycle. We also demonstrated excellent selectivity toward lithium over competing ions like calcium and cobalt, which is critical in real-world leachates. Our optimized electrode materials and cycling strategies improve both the performance and lifetime of the electrochemical recovery system.

We acknowlege the contributions of all co-authors (Stefanie Arnold, Lei Wang, Dr Rudi Mertens, and Sascha Wieczorek).

Thrilled to see our 2023 paper “The many deaths of supercapacitors: Degradation, aging, and performance fading” is among the 10 most cited articles of 2023 of the high-impact factor journal Advanced Energy Materials.

New paper published in ACS Applied Polymer Materials. This joint work with Markus Gallei from Saarland University has developed smart core–shell particles with imidazole-functionalized shells that respond to acidic solutions and hydrophobic anions, forming viscoelastic opal films with tunable structural colors. These films serve as affordable optical sensors, changing color in response to environmental stimuli, with potential applications in life sciences, environmental monitoring, and electrochemistry.

New paper in Energy & Environmental Materials: Dry Electrode Processing for Free-Standing Supercapacitor Electrodes with Longer Life, Higher Volumetric Outputs, and Reduced Environmental Impact.

Our research explores the benefits of dry electrode processing for supercapacitors. As one of the pioneering energy storage systems to adopt dry electrode processing (e.g., through [formerly] Maxwell), supercapacitors have shown significant advancements in this area. Our study follows up with this processing technology and demonstrates notable improvements in electrode lifespan, volumetric energy density, and environmental sustainability by utilizing dry processing techniques. By bypassing conventional solvent-based methods, we achieved a 28% increase in energy density and a reduction in manufacturing-related CO₂ emissions, while also extending the lifespan of supercapacitors across various electrolytes, including organic, ionic liquids, and quasi-solid state.

In the broader context, this research contributes to the ongoing efforts to enhance energy storage technologies. Supercapacitors are crucial for bridging the gap between batteries and capacitors, offering rapid charge/discharge capabilities and long cycle life. The adoption of dry electrode processing can advance their sustainability and, at the same time, yield a better performance per the more intricate particle-particle contact and ability to obtain even ultra-thick electrodes (in our work: up to 700 µm).

Team Jena: Marius Hermesdorf, Desirée Leistenschneider; Team Saarbrücken: Emmanuel Pameté, Jean Gustavo De Andrade Ruthes, Anna Seltmann, Delvina Tarimo (PhD).