New paper published in ACS Applied Energy Materials on cathode electrolyte interphase formation in lithium sulfur batteries

New paper published in ACS Applied Energy Materials. This collaborative work explores the electrochemical pathway behind cathode-electrolyte interphase (CEI) formation in Li-S batteries operated with carbonate-based electrolytes. By using microporous carbon-sulfur cathodes and tracking the first discharge, we propose an electrochemical nucleophilic mechanism in which polysulfides and solvent molecules react inside confined pores, forming a CEI that is largely LiF-rich. This interphase effectively seals carbon pores, limits further solvent intrusion, and can improve cycling stability – offering new design principles for more practical carbonate-based Li-S systems. Authors: Francisco J. García-Soriano, Jan Jerovsek, Santiago A. Maldonado-Ochoa, Fabian Vaca Chávez, Delvina Japhet Tarimo, Bostjan Genorio, Marc Florent, Teresa J. Bandosz, Robert Dominko, Christian Prehal, Alen Vizintin.