New paper published in Battery Energy on intraparticle effects on lithium-sulfur battery performance

New collaborative paper published in Battery Energy on “Intraparticular inhomogeneity limits capacity in lithium sulfur batteries with carbonate electrolyte”. This work shows that the performance of lithium-sulfur batteries with carbonate electrolytes is strongly governed by how the cathode-electrolyte interphase (CEI) forms inside nanoporous carbon host particles during the first discharge. Using cryogenic electron microscopy together with electrochemical analysis, we found that the CEI is not a uniform surface film but develops heterogeneously into the particle, leaving larger particles with inactive interior regions and therefore lower sulfur utilization. The results show that reducing carbon particle size improves capacity and rate performance, while also providing clear design guidelines for more efficient solid-state Li-S cathodes. Collaborative work with the groups of Christian Prehal and Alen Vizintin.