New paper published in Desalination on capacitive deionization studied with operando X-ray transmission

New paper published in Desalination on position-resolved ion concentration from operando X-ray transmission. This collaborative work introduces position-resolved operando synchrotron X-ray transmission to directly map local ion concentration changes inside a working capacitive deionization (CDI) cell – separating contributions from the flow channel electrolyte and the two nanoporous electrodes. Using a CsCl model electrolyte, we show how flow rate creates strong spatial gradients along the channel and how ionophobic ultramicropores (< ~0.7 nm) can dominate performance by promoting counter-ion adsorption and higher charge efficiency. Authors: Max V. Rauscher, Richard Kohns, Malina Seyffertitz, Sebastian Stock, Sylvio Haas, Christian Prehal, Nicola Hüsing, Oskar Paris.